It's hard to tell but that looks like a thin blue-green coating, which would indicate corrosion of the brass. I would not expect your original recipe to cause corrosion problems. It does have 70+ sulfate, but given the alkalinity should not be a corrosion issue. Note that the TWW espresso formula has over 100 mg/L sulfate, along with lower bicarbonate, and people don't seem to be seeing corrosion effects. Corrosion is complex, and maybe yours is is related to aggressive water used in a QA test of the new machine followed by a long dry spell on the shelf. I'd suggest cleaning those valves and watching them going forward. Ideally they'll develop a dull dark protective oxide coating over time.
Dimon Soyon wrote:I changed my recipe straight away for this one (photo below) after contacting Jonathan Gagné from Coffee ad Astra:
- Volume: 5gal / 18.9L
- Epsom salt: 2.81g
- Sodium Bicarbonate: 1.06g
- Calcium chloride (CaCl2) anydrous: 0.41g or 0.54g if it's calcius chloride dihydrous
Now that's unquestionably a move in the wrong direction if you want less corrosion. It has less alkalinity than your original water, and is slightly below the usual recommendation of 40 mg/L or more alkalinity for corrosion protection reasons.
But far more worrisome is that chloride. Any chloride may be corrosive, especially to copper and brass and especially if alkalinity is low. At 26 mg/L of chloride ion it's barely within the La Marzocco recommendation of 30 mg/L or less, but well above the Synesso recommendations of 5-15 mg/L or less.
When making water for use in espresso machines I'd recommend just steering clear of any chloride salts. I've generally followed the advice of Robert Pavlis with respect to corrosion and espresso machines -- Dr Pavlis was a professor of chemistry and expert in copper/brass corrosion, HB member name rpavlis, who passed away a few years ago. He was adamant about avoiding any chloride, and debunked the old idea of 'protective calcium carbonate scale'.
Many people on HB use his recipe of 100 mg/L potassium bicarbonate to get 50 mg/L alkalinity, zero hardness minerals, zero chloride, and zero sulfate. You could meet his recipe partway by using your original recipe, trying it with no Epsom salt, and maybe trying again with about half as much Epsom salt as your initial recipe. If adding the Epsom does not make it taste better then just don't use it.