by mj109 on Thu Mar 17, 2011 12:45 pm
As I was scrubbing away I saw some discoloration in the corrosion, some reds and greens. In order to limit myself from possible poisonous copper compounds, I was considering electroplating the broiler in a nickle or chromium, and dove into some searching on the possible negative effects of doing so. Here was a response I found interesting.
Question:
"1) the boiler is made of copper (brass?), and appears to be plated with a dull grey metal (not scale, maybe nickel?). someone has over zealously acid-cleaned/scoured about 1/3 of this plating away inside the boiler. do you think there is any significant lead leaching into the boiler water, or danger from the nickel plating continuing to "flake" off?
2) the portafilter (handle that holds the coffee grounds) is made of brass, and was chrome plated. the chrome is mostly worn away from scouring, but bits remain on the edge. again, is it dangerous to have this chrome plate potentially flake off and end up in the coffee?"
Answer:
"You are of course correct in saying that lead is added to some brasses. The amount is normally about 2-3% by weight and it is called "free machining brass". The lead acts as a dry lubricant and smears over the cutting surface. This is good for machining brass, but creates a problem if the brass is electroplated because instead of plating into copper or zinc, you are plating onto a possibly poorly adhering layer of lead. Ideally the lead should be removed by careful cleaning prior to plating, but it is not easy to do. Hence, it is best practise to use lead-free brass if you are going to electroplate the material.
Some manufacturers will plate brass or copper to either make it look pretty or perhaps to prevent corrosion. Generally copper does not corrode in water, although there are a few circumstances when that is not true, but for 99.9% of the time, we can assume copper does not corrode. Brass, however, is more likely to, due to attack of the zinc. So, plating can reduce attack if it acts as a barrier between the brass and the water. However, the plated parts will be subjected to thermal cycling between room temperature and 100C (or more if it is the element that is plated) and this could ultimately result in a delamination of the plated layers from the substrate. Consequently it is not a recommended good practice to plate such components. However, if we assume the substrate is copper or zinc, the most likely plating is nickel followed by chromium. Cheaper plating may just be nickel, but of the article is left in water for some considerable time and then allowed to dry off, the nickel will slowly turn green due to the formation of nickel salts. The time this takes depends on the water composition (tap water is not just pure H2O!). If the nickel is plated with chromium, it will remain shinier much longer.
As far as chromium is concerned, all chromium metal is Cr(0), that is it has no valence, or oxidation state. However, if it is attacked, or "oxidized" to make it dissolve, the resulting chromium salt will be either Cr(III) or some other oxidation state. Chromium can take on numerous oxidation states, but the most "unhealthy" is Cr(VI) or "hexavalent" chromium. These compounds are often seen as orange or yellow in colour. It must be stressed, if you have chromium as just the metal, you CANNOT have hexavalent chromium present.
Finally, I reiterate my comments about metal flakes, namely these should not be knowingly drunk, as they could damage the gastric tract. I would not be too concerned about your coffee attacking the chromium, as we have used stainless steel vessels and utensils of preparing food and beverages (including coffee)for many years and there has been no cited evidence of chromium poisoning from foods or drinks prepared with these tools."
I am not plating my boiler.