by another_jim on Sat Apr 09, 2011 3:52 pm
Sugar are never created in a roast. Bad roasting, i.e. too fast or too slow destroys them to no avail.
In the context of competent roasts, you have a choice how to change the sugars into other flavors. If you roast slow to the first crack, and finish fast (aka Diedrich's profile), the sugars will combine with amino acids to form Maillard reaction compounds - malt, toast, new oak, and broth-like (savory/umami) flavors. If you take it to the first crack fast, using upo fewer sugars, the remaining ones will caramelize into candy like tastes.
Roast too slowly, and the Maillard and caramel compounds polymerize into long chain, inert compounds; too fast, and you get the scorched flavors. One of these sequences has the ominous name of Strecker Degradation, but I'm not sure which one.
Cupping roasts, as fast and light as possible, retain the most straight sugars and sweetness, but also the most acids and some of the chlorogenic (grassy tasting) compounds. So their overall taste balance is rarely as sweet as darker or more leisurely roasts.
The sweetest possible taste, as opposed to the most sugar, is a balancing act. I tend to get it at medium fast roasts (11 to 13 minutes) stopped just ahead of the second crack. But I'm guessing that is equipment dependent. It also depends on how tolerant you are to unsweetened acidic and bitter tastes. For instance, to an acid lover, a given light roast may taste sweet, while to less of an acid head, it would tastes sour.
How these reactions are affected by the instantaneous heat flux, i.e. proportional to ET-BT, versus the total heat transfer, i.e proportional to the integral of the ET-BT over roast time, I have no clue.