Personally I've never seen wire in an auto parts store I'd trust under the hood of a car, let alone inside an espresso machine. Modern cars use S, G or TXL wire which is a much more heat resistant wire, 125C, the hook-up wire at most auto parts stores is only rated 176F or so, enough if you're very careful routing it, but not nearly enough if anything goes wrong. My Brutus is wired with Fiberglass wrapped silicon insulated wire which is probably good to 400F and would seem like a lot better choice if you can find it.
You can get 25' pieces of SXL wire and high temp terminals at
http://www.wiringproducts.com. Not to say you can't do better but for some reason finding high temp wire is always difficult. These people sell really high temp wire,
http://www.infraredheaters.com/wires.htm, but they have a $25 minimum and the wire is about $1 per foot.
Ira