Probably not, the extracted coffee solution being exposed to hot water is a lot different than exposing the
ground coffee puck to higher temperature.
That being said, the drink will likely be too hot to serve properly, and your crema gets obliterated when you add water to the shot(s). Ideally, you want to pull your espresso shots on top of the hot water. It is a lot prettier that way. Pull your water first, this warms the cup and lets the water cool a bit too (especially on most traditional HX machines that just have a down tube into the boiler side of the HX.... this water is flash boiled out and quite hot).
Order of ingredients discussed recently
here.
EDIT - I just re-read your question... No, you do not want to use 185 degree water for your extraction.