Assuming the boiler remains at temperature, there is only one reason the group gets cold : NO Flow.
There are two possibilities for No Flow :
Blockage seems unlikely in this case as evidenced by the change in water discharge when cool.
Which leaves Vapor Lock.
Review the images in E61 Group Espresso Machine: Detailed Interior Schematics
Brew Path Close-up and
anotatedAssuming none of the mechanical HX connections began leaking after descale, it can only be one of a few places
Brew Valve
Upper Group Sleeve Chamber Seal
OPV
1-way Valve back through pump
As the first two items were disturbed, check there first.
- If the Brew seal is leaking, water should drip from the bottom of the group. After brewing a shot, remove the drip tray, wipe the whole bottom of the group dry and see if an ever increasing puddle collects over the next hour.
- If the Upper HX chamber seal is leaking, water may be visible on an extended blind filter run. Run the pump for a full minute and check for the tiniest drop around the seals. This may also help flush the OPV.