The metal shield which surrounds the lower portion of your grouphead may very well be held in place by the fittings where the arrow in your first pic points. In any event, remove those fitting(s), remove the metal shield and remove the single nut which likely holds the solenoid coil in place.
Slide the solenoid coil (3) off and you should see something similar to the below pic (but in an assembled state

)

Unscrew the cylinder (2) and inspect the spring on the "piston" (1) for breakage. The squarish brass part which remains attached to the grouphead has a seat for the piston (1) and a water feed hole of about 1.0 mm in diameter. Inspect this seat for any buildup of minerals (rare) and wipe clean with a green scrubby. Soak 1 & 2 in hot backflushing detergent for 15-20 minutes and rinse clean. As necessary, soak 1 & 2 in white vinegar for about 30 minutes. Rinse, reassemble and you should be home-free.
I do not believe your pressure is a problem - 100 psi would exert a force of about 2 ounces on the piston.