For checking and descaling the tube I would totally remove it and test and clean it outside the machine. Take a peek at the boiler port with the tube out and make sure you don't see a bunch of scale.
I disconnected the copper line from the boiler port to the pstat and it didn't seem to have great flow, but I'm not sure what great is since it's a pretty narrow (1/4" OD?) line. I did try to descale it and seemed to flow a little better.
I can't really get a good look at the boiler port, but I was able to freely poke a safety pin into it so I don't
think it's overly obstructed.
However, once I got the new pstat installed I had the same problem: boiler pressure is way high, steam continues to leak slowly from the relief valve pin and heating element cycles off and on every few seconds. I did notice that the line from the boiler to the pstat is cold though. Perhaps there really is an obstruction between the boiler and the pstat?