by kschendel on Wed Feb 09, 2011 1:07 pm
Brass is copper and zinc. What "chemicals" exactly are you concerned about? Stainless steel is iron, chromium, and small amounts of all sorts of other stuff depending on the specific alloy (carbon, nickel, molybdenum, and manganese are typical). It's extremely likely that your entire household water supply piping is based on copper and brass.
Stainless steel strikes me as a lousy boiler material. It's hard to work and repair (much more difficult than brass), gets weird with like-material connectors, and has poor heat transfer characteristics. A very quick google search seems to indicate that most if not all espresso machines using stainless boilers are of the Saeco and DeLonghi ilk, which to me means that the stainless is there for marketing appeal rather than performance.
I'd suggest not worrying about the boiler material and going for a machine that performs well.